电子吸收的光谱学

作　者：	J-R Lalanne
出版社：	东南大学出版社
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作者简介

暂缺《电子吸收的光谱学》作者简介

内容简介

This book， a companion volume to Electronic Structure and Chemical Bonding （World Scientific， 1996）， is concerned with the teaching of optical spectroscopies of electronic absorption. It is the culmination of about ten years of experience in the teaching of the subject and the training of students to become teachers in the physical sciences.　The book covers topics of current research and includes about 30 problems with solutions， most of which are adapted from tests proposed recently at the "Aggregation" in chemistry and physics. It provides as much coverage of elementary quantum mechanics， group theory and the electronic structure of molecules as is necessary for the reader to understand the rest of the topics. Also included are numerous appendices， often presented as charts to facilitate assimilation， as well as short bibliographies， limited to basic books and review articles.　This volume will be an invaluable guide for teachers and potential teachers in the physical sciences， and more generally for stu...

图书目录

Preface

Acknowledgments

Symbols

PART I Theoretical Frame

Chapter I.- Introduction

Chapter II. - Classical Theory of Light

II. 1. Introduction: The different representations of light

II.2. Classical theory of light

　　II.2.1. Electromagnetism and Maxwell's equations

　　　II.2.1.1. Maxwell's equations

　　　II.2.1.2. The wave equation

　　II.2.2. Three solutions for Maxwell's equations

　　　II.2.2.1. The spherical wave

　　　II.2.2.2. The plane wave

　　　II.2.2.3. Gaussian wave

　II.3. Exercises and problems

　　II. 3.1. Electromagnetic wave propagation in vacuum

　　II.3.2. Search for a particular Gaussian solution of the wave equation

　　II.3.3. Treatment of Gaussian wm,es with lenses

　II.4. Appendices

　　II.4.1. Table of electromagnetic waves

　　II. 4.2. Various forms of the Maxwell's equations

　　]1.4.3. Three particular solutions to the wave equation

　II.5. Bibliography

Chapter HI- Matter and its properties

　III. 1. Non relativistic quantum mechanics

　　III.1.1. Fundamental principles and brief history

　　　III. 1.1.1. Probabilistic description

　　　III. 1.1.2. The problem of measurement and operators

　　III.1.2. Principles of the non relativistic quantum theory

　　　III.l.2.1. Postulates concerning the description of the system

　　　 III. 1.2.2. Principles for the measurement of physical quantities

　　　 III. 1.2.3. Evolution principle

　　　 III.1.2.4. Correspondence principle

　　　 III.1.2.5. Spin creation principle

　　　 III. 1.2.6. Antisymmetrization principle

　III.2. Symmetry and group theory

　　 III. 2.1. Symmetry elements and svmmsetry operations

　　 III.2.2. Representation of an operation by an operator

　　 III.2.3. Group structure and classification

　　 III.2.4. Group representation

　　　 III.2.4.1. Introduction to the notion of representation

　　　 III.2.4.2. Representation properties

　　　 III.2.4.3. Direct product of two representations

　III.3. Application of quantum mechanics and group theory to the description of stationary electronic states in atoms and molecules

　　 III.3.1. Description of the electronic structure of the hydrogen atom and of the　hydrogenic atoms

　　　 III. 3.1.1. Solution of tile eigenvalue equation for tile Hamiltonian operator

　　　 IlI.3.1.2, Energy and shell model

　　　 III.3.1.3. State vector and atomic orbital multiplicity

　　　 III.3.1.4. Various representations of probability densities in real space

　　　 III.3.1.5. Spin orbit coupling

　　 III.3.2. The description of the electronic structure of many-electron atoms

　　 III.3.2.1. Central field approximation

III.3.2.2. Electrostatic and magnetic interactions: Russel-Saunders and spin-orbit couplings

III.3.2.3. Description of configurations

　　　　III.3.3.Description of electronic structure of molecules

　　　　III.3.3.1. General presentation

　　　　Ill.3.3.2. Methods for solving the electronic eigenvalue equation

　　 III.3.4. Vibrational and rotational structure of electronic levels in atoms　and molecules

　　　 IlI.3.4.1. Vibrational structure

　　　 III.3.4.2. Rotational structure

　　　 III.3.4.3. Vibration-rotation interaction

　　III.3.5. Conclusions and consequences about electronic levels

　IlI.4. Exercises et problems

　　III.4.1. Questions about symmetry: true or false?

　　III.4.2. General aspects of LCAO theory

　　III.4.3. Study of the orbitals of 1, 3 butadiene

　　III.4.4. Energy ofsinglet and triplet states of a two-electron system

　III.5. Appendices

　　III.5.1. Main properties of linear transformations and matrices

　　III.5.2. Representation of an operator by a matrix

　　III.5.3. Tables of the postulates of quantum theory

　　III.5. 4. Tables of characters of the symmetry groups used in this book

　III.6. Bibliography

……

PART II Optical Spectroscopies of Electronec Absorption

INDEX